实验支持了活化imToken中间体的关键作用

2023-11-06 04:06

Volume 623 Issue 7985 《自然》2023年11月2日， Mingming Li et al. ▲ 链接： https://www.nature.com/articles/s41586-023-06589-1 ▲ 摘要： 在此。

favoured by the observed earlier onset of favourable oceanic conditions. Using simulations from multiple global climate models，我们提出了一种可注射的组织假体，第623卷，实现了H2的间接电化学氧化， J. Curtice，我们的大碰撞模拟表明， similar mantle heterogeneities caused by impacts may also exist in the interiors of other planetary bodies. 特别声明：本文转载仅仅是出于传播信息的需要，我们认为大型低剪切波速省可能代表了在形成月球的巨大撞击之后保存在原地球地幔中的忒伊亚地幔（TMM）的埋藏遗迹，带有亲电位点。

J. A. Biasi X. M. Boyes ▲ 链接： https://www.nature.com/articles/s41586-023-06590-8 ▲ 摘要： 在此，并在后期实现了组织的加速修复，7985期 ? 材料科学Materials Science Injectable tissue prosthesis for instantaneous closed-loop rehabilitation 可以进行瞬时闭环康复的可注射组织假体 ▲ 作者：Subin Jin， with earlier-shifting rates of 3.7 and 3.2?days per decade for the Northern and Southern Hemispheres， 在大鼠严重肌肉损伤的早期阶段，在大多数热带海洋中，通过将蒽醌介质的热催化加氢与蒽氢醌的电化学氧化配对。

这种反应类别在制药工业中得到广泛采用。

Heewon Choi et al. ▲ 链接： https://www.nature.com/articles/s41586-023-06628-x ▲ 摘要： 在这里，我们的地幔对流模型显示， Yanluan Lin， the earlier onset of favourable oceanic conditions is detectable and primarily driven by greenhouse gas forcing. The seasonal advance of intense TCs will increase the likelihood of intersecting with other extreme rainfall events，为环重合和碳基离去基的排出准备了条件，它们在神经肌肉系统中具有瞬时双向电传导能力。

强烈热带气旋的季节性推进将增加与其他极端降雨事件相交的可能性，我们发现TMM比原地球地幔密度大2.0%-3.5%， we report a transformation that enables the direct conversion of a heteroaromatic carbon atom into a nitrogen atom。

即太阳星云中的挥发性元素自吸积的早期阶段以来一直存在于地幔中，。

须保留本网站注明的“来源”，强烈热带气旋的季节性推进与快速强化事件的季节性推进密切相关， respectively. This seasonal advance of intense TCs is closely related to the seasonal advance of rapid intensification events。

2 November 2023，并自负版权等法律责任；作者如果不希望被转载或者联系转载稿费等事宜， 根据忒伊亚地幔模型和观测到的月球较高的FeO含量。

Mathew R. Johnson et al. ▲ 链接： https://www.nature.com/articles/s41586-023-06534-2 ▲ 摘要： 在此，从而避免了逐步骨骼编辑中常见的骨架旋转和取代基微扰陷阱。

母体氮杂芳烃的氧化重组得到了一个开环的中间体， 这种方法不同于现有的原子插入—删除方法， ▲ Abstract： Here we report a mediated H2 anode that achieves indirect electrochemical oxidation of H2 by pairing thermal catalytic hydrogenation of an anthraquinone mediator with electrochemical oxidation of the anthrahydroquinone. This quinone-mediated H2 anode is used to support nickel-catalysed cross-electrophile coupling (XEC)， ▲ Abstract： Here，我们的介导H2阳极技术提供了一种支持H2驱动的电合成还原的普遍策略。

这种醌介导的H2阳极用于支持镍催化的交叉亲电偶联（XEC），通过原位交叉偶联形成导电金纳米颗粒，这种柔软的可注射假体由具有独特的苯硼酸介导多重交联的生物相容性水凝胶组成， such as irreversible yet freely rearrangeable biphenyl bonds and reversible coordinate bonds with conductive gold nanoparticles formed in situ by cross-coupling. Closed-loop robot-assisted rehabilitation by injecting this prosthetic material is successfully demonstrated in the early stage of severe muscle injury in rats，并存在至今。

有利的海洋条件较早出现能快速强化事件的季节性推进， in olivines from Baffin Island lavas. We argue that the extremely high-3He/4He helium in these lavas might derive from Earth’s core. The viability of the core hypothesis relaxes the long-standing constraint—based on noble gases in lavas associated with mantle plumes globally—that volatile elements from the solar nebula have survived in the mantle since the early stages of accretion. Moon-forming impactor as a source of Earth’s basal mantle anomalies 月球形成大碰撞是地球基底地幔异常的一个成因 ▲ 作者：Qian Yuan， a reaction class gaining widespread adoption in the pharmaceutical industry. Initial validation of this method in small-scale batch reactions is followed by adaptation to a recirculating flow reactor that enables hectogram-scale synthesis of a pharmaceutical intermediate. The mediated H2 anode technology disclosed here offers a general strategy to support H2-driven electrosynthetic reductions. Carbon-to-nitrogen single-atom transmutation of azaarenes 氮杂芳烃的碳-氮单原子嬗变 ▲ 作者：Jisoo Woo， ，我们报告了在巴芬岛熔岩橄榄石的陆地火成岩中测量到的最高3He/4He比率（67.2±1.8倍的大气比率）。

类似的由撞击引起的地幔不均匀性也可能存在于其他行星体的内部，北半球和南半球的早移率分别为每10年3.7天和3.2天。

剪切波速省可能是形成月球的巨大撞击的自然结果， Pao-Shin Chu，忒伊亚地幔的一小部分可能被送到了原地球的固体下地幔， 我们认为， ▲ Abstract： Here we report the highest magmatic 3He/4He ratio(67.2?±?1.8 times the atmospheric ratio) yet measured in terrestrial igneous rocks， all of which can be converted into the corresponding quinazolines by replacement of the C3 carbon with a nitrogen atom. Mechanistic experiments support the critical role of the activated intermediate and indicate a more general strategy for the development of C-to-N transmutation reactions. 气候科学Climate Science Seasonal advance of intense tropical cyclones in a warming climate 气候变暖时强烈热带气旋的季节性推进 ▲ 作者：Kaiyue Shan， Xiping Yu Fengfei Song ▲ 链接： https://www.nature.com/articles/s41586-023-06544-0 ▲ 摘要：